应用
1,7-Octadiyne is an useful bifunctional chain extension unit. It participates in the formation of uranium(IV) vinyl complexes. It reacts with frustrated Lewis pair P(o-tolyl)3/B(C6F5)3 by acetylene C-C coupling to yield the zwitterionic product. It undergoes the reductive cyclization during reaction with Re2Cl4(?-dppm)2 (dppm = Ph2PCH2PPh2) and affords quadruply bonded dirhenium(III) complex Re2Cl3(?,η2-C8H7)(?-dppm)2.

备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Recommended storage temperature is 2 - 8°C. Incompatible with strong oxidizing agents.

基本信息

MDL
MFCD00008580

EINECS
212-815-0

分子式
HC≡C(CH₂)₄C≡CH

分子量
106.17

沸点
135-136°

闪点
23°(73°F)

密度
0.810

折射率
1.4460

灵敏度
Keep Cold.

形态
Liquid

溶解性
Not miscible or difficult to mix.

Beilstein
1697275

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H315-H319-H335-H304
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.May be fatal if swallowed and enters airways.

Precautionary Statements
P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Keep away from heat/sparks/open flames/hot surfaces. - No smoking.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险等级
3

包装组
III

危险类别
10-36/37/38-65
Flammable.Irritating to eyes, respiratory system and skin.Harmful: may cause lung damage if swallowed.

安全等级
16-26-37-62
Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.

欧盟危险品标志

TSCA
是