应用
1-Methoxy-2-methyl-1-(trimethylsiloxy)propene is used in the synthesis of chiral β-lactams by reacting with (S)-alkylidene(1-arylethyl)amines in the presence of titanium tetrachloride. It acts as a catalyst or initiator in the group-transfer polymerization. It is also used as a versatile reagent in conjugate addition4 and aldol reactions.
备注
Moisture Sensitive. Incompatible materials are Strong oxidizing agents and Strong acids. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
基本信息
MDL
MFCD00010232
EINECS
000-000-0
分子式
C8H18O2Si
分子量
174.32
沸点
35-36°/15mm
闪点
30°(86°F)
密度
0.858
折射率
1.4150
灵敏度
Moisture Sensitive. Ambient temperatures.
溶解性
Hydrolyzes in water.
Beilstein
1362893
GHS危害和防范说明
GHS符号
Hazard Statements
H226-H315-H319-H335
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
3
包装组
III
危险类别
10-36/37/38
Flammable.Irritating to eyes, respiratory system and skin.
安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
TSCA
否
