应用
(Iodomethyl)trimethylsilane is used for the N-alkylation of amides, in a reaction sequence to prepare unstabilized ylides for [2+3]-cycloadditions. It can react with acetoacetic acid ethyl ester to get 3-trimethylsilanyl-proπonic acid ethyl ester.

备注
Light Sensitive. Store in cool, dry conditions in well sealed containers. Keep container tightly closed.

基本信息

MDL
MFCD00001077

EINECS
224-123-6

分子式
C₄H₁₁ISi

分子量
214.12

沸点
140-142°

闪点
31°(88°F)

密度
1.443

折射率
1.4915

灵敏度
Light Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Difficult to mix.

Beilstein
1731485

GHS危害和防范说明

GHS符号

Hazard Statements
H226-H315-H319-H335
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.

Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

安全信息

危险等级
3

包装组
III

危险类别
10-36/37/38
Flammable.Irritating to eyes, respiratory system and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
否