应用
3,5-bis(trifluoromethyl)pheny1- magnesium iodide was prepared from 1-iodo-3,5- bis(trifluoromethyl)benzene. Monodeprotected masked hexayne was not particularly stable and hence was used directly without purification in a Sonogashira coupling with 1-iodo-3,5-bis(trifluoromethyl)benzene to provide mono-aryl-end-capped masked hexayne.
备注
Light Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, light.
基本信息
MDL
MFCD00040837
分子式
C8H3F6I
分子量
340.01
沸点
62-64°/12mm
闪点
74°(165°F)
密度
1.919
折射率
1.4645
灵敏度
Ambient temperatures.
形态
Liquid
溶解性
Slightly soluble in water.
Beilstein
2461627
GHS危害和防范说明
GHS符号
Hazard Statements
H227-H315-H319-H335
Combustible liquid.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P210e-P261-P280a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险类别
36/37/38
Irritating to eyes, respiratory system and skin.
安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
TSCA
否