应用
2(5H)-Furanone is employed in the preparation of 5-substituted 2(5H) furanones (gamma-butenolides) catalyzed by bifunctional aminothiourea and aminosquaramide organocatalysts through direct aldol reaction with aromatic aldehydes. Further, it is used in the synthesis of lignans by Michael addition reactions. In addition to this, it is used in three-component Michael-Aldol reactions with an aldehyde and thiolate or carbanion.
备注
Light and moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.
基本信息
MDL
MFCD00005376
EINECS
207-839-3
分子式
C4H4O2
分子量
84.07
熔点
3-4°
沸点
212-214°
闪点
101°(213°F)
密度
1.197
折射率
1.4690
灵敏度
Keep Cold. Light Sensitive. Store under Nitrogen.
溶解性
Immiscible with water.
Beilstein
383585
GHS危害和防范说明
GHS符号
Hazard Statements
H315-H319
Causes skin irritation.Causes serious eye irritation.
Precautionary Statements
P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313
Wear protective gloves and eye/face protection.Wash thoroughly after handling.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Specific treatment (see label).If skin irritation occurs: Get medical advice/attention.If eye irritation persists: Get medical advice/attention.
安全信息
危险类别
36/38
Irritating to eyes and skin.
安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RTECS
LU3453000
TSCA
否
