应用
1-Formylpiperidine reacts with Grignard or alkyllithium reagents gives aldehydes in high yield. It can be used as a polar aprotic solvent, with better hydrocarbon solubility than other amide solvents such as dimethylformamide. In some formylation reaction of alkyllithium compounds it gives higher yields than the DMF.
备注
Incompatible materials are oxidizing agents. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
基本信息
MDL
MFCD00006483
EINECS
219-986-0
分子式
C6H11NO
分子量
113.16
熔点
-31°
沸点
222°
闪点
102°(215°F)
密度
1.019
折射率
1.4840
灵敏度
Ambient temperatures.
形态
Liquid
溶解性
Freely soluble in water.
Beilstein
107697
GHS危害和防范说明
GHS符号
Hazard Statements
H302-H311-H315-H319-H335
Harmful if swallowed.Toxic in contact with skin.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P261-P280-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/protective clothing/eye protection/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
6.1
包装组
III
危险类别
21/22-36/37/38
Harmful in contact with skin and if swallowed.Irritating to eyes, respiratory system and skin.
安全等级
26-36/37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.
欧盟危险品标志
RTECS
TN0380000
TSCA
是