应用
Ethyl nitroacetate has been used in the synthesis of γ-oxoacids via Michael addition reaction with α,β-unsaturated ketones, fuctionalization of C4-position on pyrimidine and C6-position on 2?-deoxyguanosine to produce novel nucleosides, facile synthesis of α,α-diisobutylglycine, synthesis of DL-4,4-difluoroglutamic acid. It is also used as an intermediate in the preparation of unsubstituted amino acids.
备注
Store away from bases and oxidizing agents. Keep the container tightly closed and place it in a cool, dry and well ventilated condition.
基本信息
MDL
MFCD00007403
EINECS
210-944-7
分子式
C4H7NO4
分子量
133.11
沸点
93-95°/10mm
闪点
92°(197°F)
密度
1.202
折射率
1.4240
灵敏度
Ambient temperatures.
形态
Liquid
溶解性
Slightly soluble in water. Soluble in chloroform and ethyl acetate.
Beilstein
1210027
GHS危害和防范说明
GHS符号
Hazard Statements
H227-H315-H319
Combustible liquid.Causes skin irritation.Causes serious eye irritation.
Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
安全信息
危险类别
36/38
Irritating to eyes and skin.
安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RTECS
AJ1074000
TSCA
是
