应用
Ethyl 1,3-dithiane-2-carboxylate is used in syn-selective aldol reactions. It undergoes asymmetric oxidation to give trans bis-sulfoxide. It is used to generate carbanon, which finds application in the preparation of alfa- keto esters.
备注
Incompatible with acids, bases, oxidizing agents and reducing agents.
基本信息
MDL
MFCD00006657
EINECS
243-838-4
分子式
C7H12O2S2
分子量
192.30
熔点
19-21°
沸点
75-77°/0.2mm
闪点
54°(129°F)
密度
1.220
折射率
1.5400
灵敏度
Ambient temperatures.
溶解性
Slightly miscible with water.
Beilstein
1424352
GHS危害和防范说明
GHS符号
Hazard Statements
H226
Flammable liquid and vapour.
Precautionary Statements
P210-P280a-P240-P241-P303+P361+P353-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves and eye/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险类别
10
Flammable.
TSCA
否
