应用
3-Ethoxy-2-cyclohexen-1-one is a useful intermediate for the preparation of 3-alkyl- or aryl-2-cyclohexen-1-ones, by addition of organometallic reagents and subsequent hydrolysis. It helps in kinetic enolate formation (LDA) and alkylation occurs at the 6-position, the Stork-Danheiser kinetic alkylation procedure, which has found extensive use in alicyclic synthesis.
备注
Store at 4?°C. Protect from heat. Store away from oxidizing agents.
基本信息
MDL
MFCD00001580
EINECS
226-190-7
分子式
C8H12O2
分子量
140.18
沸点
76-78°/1mm
闪点
107°(224°F)
密度
1.04
折射率
1.5060
灵敏度
Store at -20°C.
形态
Liquid
溶解性
Slightly soluble in water.
Beilstein
2042049
安全信息
TSCA
否