应用
Diphenyl sulfoxide is a reagent used as an oxidant and hydroxyl activator in combination with a variety of electrophilic reagents. Efficient glycosidation of a phenyl thiosialoside donor with diphenyl sulfoxide and triflic anhydride in dichloromethane was reported. Direct glycosylations with 1-hydroxy glycosyl donors is made using trifluoromethanesulfonic anhydride and diphenyl sulfoxide. The preparation of triarylsulfonium halides was by the action of aryl Grignard reagents on diphenyl sulfoxide.
备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
基本信息
MDL
MFCD00002085
EINECS
213-415-9
分子式
C12H10OS
分子量
202.28
熔点
69-72°
沸点
206-208°/13mm
灵敏度
Ambient temperatures.
形态
Crystalline powder
溶解性
Soluble in water. Soluble in most organic solvents.
Beilstein
1908444
安全信息
RTECS
DA9185000
TSCA
是