应用
N,N-Dimethylformamide di-tert-butyl acetal is used as a reagent in the synthesis of (S)-2-(1-tert-butoxycarbonyl-2-{4-[2-(5-methyl-2-phenyloxazol-4-yl)ethoxy]phenyl}ethylamino)benzoic acid methyl ester, 3-O-tert-butylmorphine, tert-butylesters of pyrrole and indolecarboxylic acids. Further, it is used in the preparation of indolizines by intermolecular cyclization of picolinium salts.
备注
Moisture sensitive. Incompatible with strong oxidizing agents and acids.
基本信息
MDL
MFCD00015002
EINECS
253-222-7
分子式
C11H25NO2
分子量
203.33
沸点
75-77°/12mm
闪点
33°(91°F)
密度
0.850
折射率
1.4120
灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
形态
Liquid
溶解性
Miscible with toluene and benzene.
Beilstein
969629
GHS危害和防范说明
GHS符号
Hazard Statements
H226-H315-H319-H335
Flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
3
包装组
III
危险类别
10-36/37/38
Flammable.Irritating to eyes, respiratory system and skin.
安全等级
23-26-37
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
TSCA
否
