应用
Diethoxymethylsilane is used in the preparation of N,N'-methylsilanediyl-bis-phthalimide by reacting with phthalimide. It is used as a reagent in the selective reduction of carbonyl compounds, hydorosilylation of alkenes, tandem reductive aldol reaction and rhodium-catalyszed silylcarbocyclization.
备注
Incompatible with oxidizing agents, acids and bases.
基本信息
MDL
MFCD00026749
EINECS
217-982-3
分子式
C5H14O2Si
分子量
134.25
沸点
94-95°
闪点
10°(50°F)
密度
0.840
折射率
1.3760
灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
形态
Liquid
溶解性
Miscible with water, 1,4-dioxane, tetrahydrofuran, acetonitrile, dichloromethane, chloroform, dimethyl sulfoxide, hexamethylphosphoric triamide and toluene. Insoluble in diethyl ether and hexane.
Beilstein
1733975
GHS危害和防范说明
GHS符号
Hazard Statements
H225-H315-H319-H335
Highly flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
3
包装组
II
危险类别
11-36/37/38
Highly flammable.Irritating to eyes, respiratory system and skin.
安全等级
7-26-33-37-60
Keep container tightly closed.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.Take precautionary measures against static discharges.This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
是