应用
It finds many applications in organic synthesis, as a catalyst and a reagent. It is used as a catalyst in Sandmeyer reaction for preparing aryl bromides from arylamines through diazonium salts. It forms complexes with Lewis bases, such as dimethylsulfide, which is a precursor to organocopper reagents. Reactions involving Atom Transfer Radical Polymerization (ATRP) and Cu-catalyzed Cross-Dehydrogenative Couplings (CDC) are catalyzed by CuBr complexes.

备注
Copper(I) bromide oxidizes easily in air, to copper(II) salt with formation of color. Store away from strong oxidizing agents, and metals.

基本信息

MDL
MFCD00010969

EINECS
232-131-6

分子式
BrCu

分子量
143.45

熔点
492°

沸点
1345°

密度
4.98

灵敏度
Air Sensitive. Store under Argon. Ambient temperatures.

形态
Powder

溶解性
Slightly soluble in cold water. Decomposes in hot water. Soluble in HBr, HCl, and ammonium hydroxide solution.

Merck
14,2659

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319-H335-H400-H410
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38-50/53
Irritating to eyes, respiratory system and skin.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

安全等级
26-37-57-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Use appropriate container to avoid environmental contamination.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是