应用
(Chloromethyl)cyclopropane was used in the synthesis of (lithiomethyl)cyclopropane and homoallyllithium via 4,4?-di-tert-butylbiphenyl or naphthalene-catalysed lithiation reaction. On reaction with isolable dialkylsilylene affords 5-silaspiro[4.4]nonane derivative.
备注
Stable under recommended storage conditions. Incompatible with oxidizing agents, bases and heat.
基本信息
MDL
MFCD00001307
EINECS
227-632-1
分子式
C4H7Cl
分子量
90.55
熔点
-91°
沸点
87-89°
闪点
-1°(30°F)
密度
0.980
折射率
1.4360
灵敏度
Keep Cold.
形态
Liquid
溶解性
Not miscible in water.
Beilstein
635697
GHS危害和防范说明
GHS符号
Hazard Statements
H225-H302-H315-H319-H335
Highly flammable liquid and vapour.Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P210-P261-P280h-P243-P305+P351+P338
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves/clothing.Take precautionary measures against static discharge.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
安全信息
危险等级
3
包装组
II
危险类别
11-22-36/37/38
Highly flammable.Harmful if swallowed.Irritating to eyes, respiratory system and skin.
安全等级
16-23-26-33-36/37
Keep away from sources of ignition - No smoking.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.Wear suitable protective clothing and gloves.
欧盟危险品标志
TSCA
否
