应用
tert-Butyl nitrite is employed as a reagent for diazotization and nitrosation of alcohols, thiols, amines and cycloalkanes. It plays an important role in photocatalyzed conversion of aryl and heteroarylamines to selenides. It finds application in the preparation of aryl azides from aryl amines. It is also useful for radical multifunctionalization reactions of aliphatic alkenes and source of nitric oxide.
备注
Light sensitive. Store in cool place. Incompatible with strong reducing agents, powdered metals and strong acids.
基本信息
MDL
MFCD00002055
EINECS
208-757-0
分子式
(CH3)3CONO
分子量
103.12
沸点
61-63°
闪点
-23°(-9°F)
密度
0.867
折射率
1.3690
灵敏度
Keep Cold.
溶解性
Miscible with diethyl ether, chloroform, alcohol and carbon disulfide. Slightly miscible with water. Immiscible with glycerol.
Beilstein
1209339
Merck
14,1583
GHS危害和防范说明
GHS符号
Hazard Statements
H225-H302-H332
Highly flammable liquid and vapour.Harmful if swallowed.Harmful if inhaled.
Precautionary Statements
P210-P262-P301-P315-P310
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Do not get in eyes, on skin, or on clothing.IF SWALLOWED:Get immediate medical advice/attention.Immediately call a POISON CENTER or doctor/physician.
安全信息
危险等级
3
包装组
II
危险类别
11-20/22
Highly flammable.Harmful by inhalation and if swallowed.
安全等级
16-24-46
Keep away from sources of ignition - No smoking.Avoid contact with skin.If swallowed, seek medical advice immediately and show this container or label.
欧盟危险品标志
RTECS
RA0802000
TSCA
否
