应用
tert-Butyldimethylsilylacetylene may be used in the synthesis of β-alkynylketone and β-alkynyl aldehydes. It participates in Cadiot-Chodkiewicz cross-coupling reaction with various bromoalkynes to afford synthetically useful unsymmetrical diynes.
备注
Stable under recommended storage conditions.
基本信息
MDL
MFCD00191877
分子式
C8H16Si
分子量
140.30
沸点
130°
闪点
6°(43°F)
密度
0.751
折射率
1.451
灵敏度
Ambient temperatures.
形态
Liquid
溶解性
Sparingly soluble in water (0.043 g/L at 25°C).
Beilstein
1921466
GHS危害和防范说明
GHS符号
Hazard Statements
H225-H315-H319-H335
Highly flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
3
包装组
II
危险类别
11-36/37/38
Highly flammable.Irritating to eyes, respiratory system and skin.
安全等级
16-26-37
Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
欧盟危险品标志
TSCA
否
