应用
(Bromomethyl)cyclopropane is used in the synthesis of 1,4-dienes by iron-catalyzed cross-coupling with alkenyl Grignard reagents. It has been used as a synthetic building block for the introduction of the cyclopropylmethyl group.
备注
Protect from heat. Store away from oxidizing agents. Incompatible with strong bases, strong oxidizing agents.
基本信息
MDL
MFCD00001306
EINECS
230-331-8
分子式
C4H7Br
分子量
135.00
沸点
111-112°
闪点
41°(105°F)
密度
1.410
折射率
1.4770
灵敏度
Keep Cold.
形态
Liquid
溶解性
Not miscible in water.
Beilstein
605296
GHS危害和防范说明
GHS符号
Hazard Statements
H226-H302-H315-H319-H335
Flammable liquid and vapour.Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
3
包装组
III
危险类别
10-22-36/37/38
Flammable.Harmful if swallowed.Irritating to eyes, respiratory system and skin.
安全等级
23-26-36/37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
否
