应用
The N-(3, 5-Dichlorophenyl) naphthaldimine was obtained from the reaction of 2-hy- droxynaphthalene-l-carbaldehyde (0.01 mol) with a solution of 2-bromo-4-methylaniline (0.01 mol) in 40 ml of ethanol. Reaction of 2-bromo-4-methylaniline was quite clean, albeit 3,4-diaminotoluene was isolated just in 37% yield after flash chromatography on silica gel. The bromomethylquinoline starting material 16 was synthesized in two steps using an optimized process route by condensing 2-bromo-4-methylaniline.
备注
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
基本信息
MDL
MFCD00007635
EINECS
209-515-7
分子式
C7H8BrN
分子量
186.06
熔点
14-16°
沸点
240-242°
闪点
>110°(230°F)
密度
1.494
折射率
1.6030
灵敏度
Ambient temperatures.
形态
Liquid
溶解性
Insoluble in water.
Beilstein
1931711
GHS危害和防范说明
GHS符号
Hazard Statements
H301-H311-H315-H319
Toxic if swallowed.Toxic in contact with skin.Causes skin irritation.Causes serious eye irritation.
Precautionary Statements
P280h-P305+P351+P338-P309-P310-P302+P352
Wear protective gloves/clothing.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF exposed or if you feel unwell:Immediately call a POISON CENTER or doctor/physician.IF ON SKIN: Wash with plenty of soap and water.
安全信息
危险等级
6.1
包装组
III
危险类别
24/25-36/38
Toxic in contact with skin and if swallowed.Irritating to eyes and skin.
安全等级
26-28-36/37-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer).Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
RTECS
XU4300000
TSCA
是
