应用
It is mainly used as the OLED pharmaceutical intermediate, as reagent for in situ desilylation and coupling of silylated alkynes, as substrate in copper-free Sonogashira coupling in aqueous acetone. It is also used in synthesis of β,β,dibromostyrenes, as starting reagent in the total syntheses of ent-conduramine A and ent-7-deoxypancratistatin (alkaloids).
备注
Light sensitive. Store in a cool, dry, well-ventilated area. Store away from oxidizing agent, light.
基本信息
MDL
MFCD00001051
EINECS
209-662-7
分子式
C6H4BrI
分子量
282.91
熔点
89-93°
沸点
252°
灵敏度
Light Sensitive. Ambient temperatures.
形态
Crystalline powder
溶解性
Insoluble in water.
Beilstein
1904545
GHS危害和防范说明
GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
安全信息
危险类别
36/37/38
Irritating to eyes, respiratory system and skin.
安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
TSCA
是