应用
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0?°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
备注
Stable under recommended storage conditions. Incompatible with oxidizing agents.
基本信息
MDL
MFCD00000568
EINECS
203-575-8
分子式
C6H4BrCl
分子量
191.46
熔点
-22°
沸点
195-196°
闪点
80°(176°F)
密度
1.630
折射率
1.5770
灵敏度
Ambient temperatures.
形态
Liquid
溶解性
Not miscible in water.
Beilstein
1446353
GHS危害和防范说明
GHS符号
Hazard Statements
H227-H315-H319-H335
Combustible liquid.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P280g-P305+P351+P338
Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
安全信息
危险类别
36/37/38
Irritating to eyes, respiratory system and skin.
安全等级
23-26-37-60
Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste
RTECS
CY9005000
TSCA
是
