应用
Used as reactant for N-Benzyl-protection of amino acid derivatives by reductive alkylation, reductive alkoxyamination, as reducing agent for the labeling of oligosaccharides by reductive amination, synthesis of alkoxyamine derivatives, via reduction of oxime ethers, reductive amination reactions of C1-C10 aldehyde 2,4-dinitrophenylhydrazones, synthesis of various trifluoromethylated amino compounds and an alternative reagent for reductive aminations.
备注
Refrigerate. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.
基本信息
MDL
MFCD07784361
分子式
C6H7N.BH3
分子量
106.96
熔点
44-50°
闪点
100°(212°F)
灵敏度
Keep Cold. Moisture Sensitive. Store under Argon.
形态
Solid
溶解性
Slightly sol. in water, cyclohexane, very sol. in methanol, THF, diglyme, and benzene
GHS危害和防范说明
GHS符号
Hazard Statements
H261-H315-H319-H335
In contact with water releases flammable gas.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P223-P231+P232-P261-P305+P351+P338-P405-P501a
Keep away from any possible contact with water, because of violent reaction and possible flash fire.Handle under inert gas. Protect from moisture.Avoid breathing dust/fume/gas/mist/vapours/spray.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险等级
4.3
包装组
II
危险类别
14/15-36/37/38
Reacts violently with water, liberating extremely flammable gases.Irritating to eyes, respiratory system and skin.
安全等级
7/8-26-30-33-37-43-60
Keep container tightly closed and dry.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Never add water to this product.Take precautionary measures against static discharges.Take precautionary measures against static discharges.In case of fire, use ... (indicate in the space the precise type of fire fighting equipment. If water increases risk, odd 'Never use water')This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
否