应用
Benzeneboronic acid is widely utilized in various cross coupling reactions for example Mizoroki-Heck and Suzuki-Miyaura coupling reactions, etc. It serves as a receptor for carbohydrates, antimicrobial agents and enzyme inhibitors in biological reactions. It acts as a reagent in palladium-catalyzed stereoselective Heck-type reaction and as a catalyst in Ni(II) pincer complex and Pd(II) pyridoxal hydrazone metallacycles. It is also employed as a sensor for neutron capture therapy for cancer, transmembrane transport and bioconjugation and labeling of proteins and cell surface.
备注
Hygroscopic. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents. Avoid moisture exposure.
基本信息
MDL
MFCD00002103
EINECS
202-701-9
分子式
C6H7BO2
分子量
121.93
熔点
214-219°
灵敏度
Hygroscopic. Store under Argon. Ambient temperatures.
形态
Crystalline powder
溶解性
Slightly soluble in water.
Beilstein
970972
Merck
14,1068
GHS危害和防范说明
GHS符号
Hazard Statements
H302-H315-H319-H335
Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险类别
22-36/37/38
Harmful if swallowed.Irritating to eyes, respiratory system and skin.
安全等级
26-36/37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.This material and its container must be disposed of as hazardous waste
欧盟危险品标志
RTECS
CY8575000
TSCA
是