应用
2-Aminobenzyl alcohol is oxidatively cyclised with an array of ketones in dioxane at 80?°C in the presence of a ruthenium catalyst and KOH to give corresponding quinolines. It undergoes oxidation catalyzed by heterotrimetallic RuMnMn species on the hydrotalcite surface in the presence of O2? to yield 2-aminobenzaldehyde. was used in the synthesis of ethyl 2-hydroxymethylcarbanilate.
备注
Store at room temperature. Incompatible with oxidizing agents.
基本信息
MDL
MFCD00007749
EINECS
226-293-7
分子式
C7H9NO
分子量
123.16
熔点
81-84°
沸点
160°/10mm
灵敏度
Keep Cold. Air Sensitive. Light Sensitive.
形态
Powder or crystals
溶解性
Very soluble in water.
Beilstein
1072211
GHS危害和防范说明
GHS符号
Hazard Statements
H315-H319-H335
Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P261-P280a-P305+P351+P338-P304+P340-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
危险类别
36/37/38
Irritating to eyes, respiratory system and skin.
安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
RTECS
DN3155000
TSCA
是
