应用
Reagent for the reduction of carbonyl compounds. Used in alcoholysis and ester exchange reactions. Also used in synthesis of higher alkoxides, chelates, and acrylates. Aluminum isopropoxide is a useful reagent in the synthesis of alkoxides, chelates and acrylates. It acts as an intermediate of pharmaceutical products like isophytol, testosterone, progesterone and ethisterone. Also used as the material of aluminate coupling agent. It is also used in alcoholysis and ester exchange reactions. In Meerwein-Ponndorf-Verley (MPV) reduction, it is used as a catalyst for the reduction of ketones and aldehydes to their corresponding alcohols.
备注
Moisture sensitive. Incompatible with strong oxidizing agents, strong acids and halogens.
基本信息
MDL
MFCD00008870
EINECS
209-090-8
分子式
Al[OCH(CH3)2]3
分子量
204.25
熔点
131-135°
沸点
135°/10mm
密度
1.035
折射率
1.0346
灵敏度
Moisture Sensitive. Ambient temperatures.
形态
Granular
溶解性
Soluble in alcohol, benzene, and toluene. Decomposes in water.Soluble in ethanol, isopropanol, benzene, toluene, chloroform, carbon tetrachloride and petroleum hydrocarbons.
Merck
14,347
GHS危害和防范说明
GHS符号
Hazard Statements
H228
Flammable solid.
Precautionary Statements
P210-P280-P240-P241-P370+P378a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves/protective clothing/eye protection/face protection.Ground/bond container and receiving equipment.Use explosion-proof electrical/ventilating/lighting/ equipment.In case of fire: Use for extinction: CO2, powder or water spray.
安全信息
危险等级
4.1
包装组
II
危险类别
11
Highly flammable.
安全等级
8-16
Keep container dry.Keep away from sources of ignition - No smoking.
欧盟危险品标志
RTECS
BD0975000
TSCA
是