应用
A sol-gel process has been developed for the chemical synthesis of ZnS at room temperature using zinc tert-butoxide and H 2 S as precursors in a toluene solution. The key step that enables this zinc-mediated epoxidation to be catalytic may be the equilibrium between zinc peroxide (R)-15 and zinc tert-butoxide (R)-16 in the presence of t-BuOOH. An additional important feature that renders the dual catalytic cycles feasible is the poor reactivity of zinc tert-butoxide toward the iridium-bound cationic intermediate, whereby the requisite deprotonation process is effectively mediated by zinc tert-butoxide.
备注
Moisture Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents, air, moisture.
基本信息
MDL
MFCD00145545
分子式
C8H18O2Zn
分子量
211.61
灵敏度
Moisture Sensitive. Store under Nitrogen. Ambient temperatures.
形态
Powder
溶解性
Insoluble in water.
GHS危害和防范说明
GHS符号
Hazard Statements
H228-H315-H319-H335
Flammable solid.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P210-P280g-P305+P351+P338
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Wear protective gloves.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
安全信息
危险等级
4.1
包装组
III
危险类别
11-36/37/38
Highly flammable.Irritating to eyes, respiratory system and skin.
安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
否
