应用
Tris(pentafluorophenyl)borane is used as an excellent activator component in homogeneous Ziegler-Natta chemistry. It is also used as a catalyst for reductions, alkylations, hydrometallation reactions and catalyzed aldol-type reactions. It is a useful Lewis acid and catalyzes hydrosilylation of aldehydes. Further, it is used in olefin polymerization catalysis. It serves as a reagent in the preparation of organometallic complexes. In addition to this, it is useful as polymerization catalysts and used to study the heterolytic cleavage of dihydrogen in associated with tri-tert-butylphosphine.

备注
Moisture sensitive. Incompatible with strong oxidizing agents and trimethylaluminum.

基本信息

MDL
MFCD00269813

分子式
C₁₈BF₁₅

分子量
511.99

熔点
126-130°

灵敏度
Moisture Sensitive. Store under Nitrogen. Store at -20°C.

形态
Powder

溶解性
Soluble in hexane, chloroform, dichloromethane, toluene, and polar solvents.

Beilstein
2931347

Merck
14,9755

GHS危害和防范说明

GHS符号

Hazard Statements
H301-H315-H319-H335-H400-H410
Toxic if swallowed.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.Very toxic to aquatic life.Very toxic to aquatic life with long lasting effects.

Precautionary Statements
P261-P280a-P301+P310a-P305+P351+P338-P405-P501a
Avoid breathing dust/fume/gas/mist/vapours/spray.Wear protective gloves and eye/face protection.Wear protective gloves and eye/face protection.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

安全信息

危险类别
36/37/38
Irritating to eyes, respiratory system and skin.

安全等级
26-37-60
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.This material and its container must be disposed of as hazardous waste

欧盟危险品标志

TSCA
是