应用
Tris(3,6-dioxaheptyl)amine acts as a phase transfer catalyst used in the preparation of 1,3-dideaza-2'-deoxyadenosine and related benzimidazole 2'-deoxyribonucleosides. It is also used as an intermediate in the synthesis of telithromycin. Further, it is used in the oxidation of arylmethanols under phase-transfer conditions. In addition to this, it acts as a cryptand during phase-transfer glycosylation of 2-amino-4-methoxy-7H-pyrrolo[2,3-d]pyrimidine.

备注
Air sensitive and hygroscopic. Incompatible strong oxidizing agents and strong acids.

基本信息

MDL
MFCD00010748

EINECS
274-590-5

分子式
N(CH₂CH₂OCH₂CH₂OCH₃)₃

分子量
323.43

熔点
<-100°

沸点
163-171°/1mm

闪点
162°(323°F)

密度
1.011

折射率
1.4486

灵敏度
Hygroscopic. Air Sensitive. Ambient temperatures.

形态
Liquid

溶解性
Miscible with water.

Beilstein
2369296

GHS危害和防范说明

GHS符号

Hazard Statements
H315-H319
Causes skin irritation.Causes serious eye irritation.

Precautionary Statements
P280a-P264-P305+P351+P338-P321-P332+P313-P337+P313
Wear protective gloves and eye/face protection.Wash thoroughly after handling.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Specific treatment (see label).If skin irritation occurs: Get medical advice/attention.If eye irritation persists: Get medical advice/attention.

安全信息

危险等级
8

包装组
III

危险类别
36/38
Irritating to eyes and skin.

安全等级
26-37
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

TSCA
是