应用
Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of "push-pull" tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.
备注
Moisture Sensitive. Store at 4?°C. Store away from oxidizing agents and strong bases. Incompatible with heat and water.
基本信息
MDL
MFCD00013121
EINECS
207-112-0
分子式
C19H15F6P
分子量
388.29
熔点
ca 160° dec.
灵敏度
Store at -20°C. Moisture Sensitive. Store under Nitrogen.
形态
Crystalline powder
溶解性
Soluble in water. (27 g/L) at 25°C.
Beilstein
4344297
GHS危害和防范说明
GHS符号
Hazard Statements
H314-H318
Causes severe skin burns and eye damage.Causes serious eye damage.
Precautionary Statements
P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P310
Wear protective gloves/protective clothing/eye protection/face protection.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.Immediately call a POISON CENTER or doctor/physician.
安全信息
危险等级
8
包装组
II
危险类别
34
Causes burns.
安全等级
20-26-36/37/39-45-60
When using do not eat or drink.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
是
