应用
Triethylsilane is used for the hydrosilation of olefins to prepare alkyl silanes. It acts as a reducing agent in the reduction of 2-chromanols, since it has an active hydride. It acts as a catalyst for redox initiated cationic polymerization, regioselective reductive coupling of enones and allenes, and Beckmann rearrangement of cyclododecanone oxime. It is associated with trifluoroacetic acid and involved in the selective reduction of alkenes.
备注
Incompatible with strong acids, water and bases.
基本信息
MDL
MFCD00009018
EINECS
210-535-3
分子式
C6H16Si
分子量
116.28
熔点
-157°
沸点
107-108°
闪点
-6°(21°F)
密度
0.728
折射率
1.4120
灵敏度
Moisture Sensitive. Ambient temperatures.
形态
Liquid
溶解性
Miscible with water.
Beilstein
1098278
GHS危害和防范说明
GHS符号
Hazard Statements
H225-H315-H319-H335
Highly flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation.
Precautionary Statements
P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.
安全信息
UN#
UN1993
危险等级
3
包装组
II
危险类别
11-36/37/38
Highly flammable.Irritating to eyes, respiratory system and skin.
安全等级
9-16-26-33-37-60
Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges.Take precautionary measures against static discharges.This material and its container must be disposed of as hazardous waste
欧盟危险品标志
TSCA
是
